Are basal Ediacaran (635 Ma) post-glacial “cap dolostones” diachronous?

A layer of shallow-water dolostone (“cap dolostone”) with idiosyncratic sedimentary structures was deposited across continental margins world-wide in the aftermath of the terminal Cryogenian snowball Earth. The dolostone has a global average thickness of 18.5 m and is interpreted stratigraphically in different ways in the current literature: as diachronous (top and bottom) and tracking glacioeustatic flooding, as semi-diachronous (bottom diachronous, top isochronous) and outlasting the flood, or as isochronous (top and bottom) and recording ocean-wide changes over time subsequent to deglaciation. Each interpretation carries a different implication for the timescale of cap dolostones and their isotopic signatures, and therefore for their origin. In northernNamibia, we studied theKeilberg cap dolostone (635Ma) across theOtavi carbonate bank and down a contiguous submarine paleoslope to estimated depths of∼0.5 km.We find giant wave ripples and other wave-generated structures in all areas, including the lower slope, pointing to a base-level change of large amplitude. No other formation in the carbonate succession contains wave-generated bedforms on the lower slope. Carbon isotope records from the bank are similar in shape and absolute value, irrespective of thickness. Slope records are also similar to one another, but different in shape and value from those on the bank. If the cap is isochronous, lower-slope waters were enriched in C by 2–3‰ compared with the bank, which seems improbable. If diachronous, the lower slope, upper slope and bank records collectively describe a sigmoidal δC curve over time with a net decline of 4.4‰. In addition, a lateral gradient of 1.0‰/ 100 km existed from the inner to outer bank. If the flooding was rapid (b10 kyr), as suggested by ice-melting models, the δC change may reflect strong surface warming, methane release, and kinetic isotope effects associated with rapid carbonate production. If the transgression was prolonged (N100 kyr), as implied by actualistic interpretation of paleomagnetic reversals in this and other cap dolostones, the δC change could record Rayleigh distillation associated with the drawdown of a large atmospheric CO2 reservoir, built up during the preceding snowball glaciation. Either way, the sedimentology and isotopes support the diachronous interpretation, and are inconsistent with the semi-diachronous and isochronous models. The base-level rise of ∼0.5 km implies a glacioeustatic origin, ⁎ Corresponding author. Tel.: +1 617 496 6380; fax: +1 617 384 8249. E-mail address: [email protected] (P.F. Hoffman). 0012-821X/$ see front matter © 2007 Elsevier B.V. All rights reserved. doi:10.1016/j.epsl.2007.03.032 115 P.F. Hoffman et al. / Earth and Planetary Science Letters 258 (2007) 114–131 meaning that cap dolostone sedimentation was synchronous with land ice melting. This leaves the actualistic interpretation of reversal frequency and speed in cap dolostones in conflict with ice-melting models. © 2007 Elsevier B.V. All rights reserved.